Read the important steps of filtering and winterizing wax in hemp extraction and how extraktLAB's DrainDroyd is the best system for the task. Winterization is necessary to create a higher purity of cannabinoids. Removing lipids results in a higher quality product. Winterization is key step in the extraction and purification of oils derived from cannabis and hemp. How is it used to remove fats and waxes from cannabinoid oils?
What You Should Know About Filtration, Winterizing Wax and CBD Extraction
After grinding, decarboxylating and extracting hemp the next important step is to filter and winterizing wax. In this article, we explain why this step is crucial to supercritical CO2 extraction.
Grow, harvest, test, grind, decarboxylate, test again, extract… What’s next? Depending on your extraction method of choice, it is very likely that the next step in creating your hemp concentrate will involve winterizing wax and filtering your mixture to begin the distillation process.
Because the crude oil that is created with methods like supercritical CO2 extraction will often contain waxes and lipids, it becomes important to remove them to create a quality final product for the consumer.
So, let’s take a look at this important process and why supercritical CO2 extraction benefits from it.
What is Winterization?
Winterization is the process of removing fats and waxes from the hemp extract. The process involves dissolving the CBD oil coming out of the CO2 extractor in food grade ethanol and subsequently chilling the ethanol oil mixture down to -20 degrees Celsius. The fats and waxes are less soluble at those temperatures and they will precipitate while the cannabinoids remain in solution. The fats and waxes are then filtered before solvent removal.
Why Winterizing Wax is Important
Because extraction will also take out plant waxes and fats with the desired cannabinoids, winterizing wax is critical to create a product that is desirable to the end user.
Winterizing wax and then filtering oil is important to remove the fats and waxes that would otherwise cause flavor and consistency issues. In vape products, for example, fats and waxes can cause a harsh flavor and can even cause irritation of the throat as well. This can all be mitigated by winterizing wax and filtering it out.
By winterizing wax, you solidify the plant fats and waxes at frigid cold temperatures while the desired components remain in a liquid form. This allows for a vacuum filtration method to be used that pulls the oil through a filtration medium that traps the waxes, fats and chlorophylls while allowing the desired cannabinoids and terpenes to be collected. This results in a higher quality product that is desirable and profitable to the end customer.
Why Winterize and Filter Your Oil?
Depending on the product that is being created, remaining waxes and lipids can cause a number of issues for both producers and consumers:
For the producer, remaining waxes and lipids can dilute product potency, and cause a lesser quality distillate overall. Quality and clarity of a hemp extract often go hand-in-hand, and remaining waxes can cause a final distillate to be cloudy or of undesired consistency – not the result a producer wants to see after all the hard work.
For the consumer, waxes and lipids left in an extract can result in a shotty product as well. For example, smokeable hemp extracts or “dabs” as they are often called can come in the form of what is called “shatter” given its translucent clarity and breakable consistency similar to glass.
Both clarity and consistency mean quality shatter and a happy customer, but when residual waxes are left in the product it can cause what is called nucleation making that clear, brittle shatter turn into a soft, sticky opaque consistency.
Furthermore, fats and waxes left in any hemp concentrate can be harsh or have undesirable tastes when smoked or vaporized. Because of this, it is very important to properly winterize and filter those remaining waxes and lipids. And, there are many methods to do this.
As a proud proponent of supercritical CO2 extraction, extraktLAB does not use denatured ethanol for an extraction method for a number of reasons. However, a common method of winterizing wax involves the use of ethanol. So, we often face a recurring question in the dewaxing process.
Why Use CO2 Extraction When You Use Ethanol for Winterization?
Though it is undoubtedly the cleaner extraction solvent, biomass, fatty acids, waxes and resins can be co-extracted along with the cannabidiol and other cannabinoids when CO2 is used to extract hemp. The amount that is extracted depends on the pressure of the CO2 extraction.
In general, the higher the pressure and longer the runtime, the more acids and waxes will be extracted. Low pressure CO2 extraction methods, known as subcritical CO2 extraction, produce extracts that require very little post processing.
Many companies actually skip the winterization process depending on what they are using the oils for. The trade-off for lowering the extraction pressure to subcritical is that the run time increases greatly. The flow rate must be increased to compensate for the lower run time. In the case of our extraction equipment, the flow rate increases as the pressure goes down so those customers desiring runs of critical methods are able to do so with significant efficiency.
In the case of supercritical CO2 extraction, winterizing wax is likely going to be needed. The cannabinoids and CBD oils that remain in the solution are then introduced into a falling film evaporator. The ethanol is removed from the solution and may be recycled once it has been re-conditioned and tested for reuse. The amount of ethanol that is used in the winterization process is very small compared to the amount of ethanol that is used during an ethanol extraction.
For example, one gallon of ethanol is required to fluidize one pound of hemp for ethanol extraction. 1000 lb of hemp by extension requires 1000 gallons of ethanol. In contrast, 1000 lb of hemp at 10% cannabinoid will produce approximately 100 lbs of CBD oil. 100 lb of CBD oil – Approximately 30 gallons Of CBD oil, so 180 gallons of ethanol is needed to winterize 30 gallons of CBD oil.
Why is the Winterization Process Important in Cannabis Oil Extraction?
The winterization process, in simple terms, is the removal of fats, lipids and other unwanted materials from crude oil extract. Winterization is necessary to create a higher purity of cannabinoids. Lipids dilute the cannabinoid fraction, therefore removing them results in a higher quality product.
The transparency of the product is also affected by lipids in distillate. When lipids are not removed, the distillate will not be transparent – this is a sign of a lower-quality and lower-valued product.
Another adverse effect that lipids have in distillate is the way that they burn on coils in vape pens. Lipids will make the vape pen taste burnt which is unsatisfactory to the consumer. Winterization is a key process that differentiates a product from being either low quality or high quality. That directly affects the value of the product that you are creating.
What is the winterization process?
During winterization, a non-polar oil extract is dissolved into ethanol or other polar solvent. The solution is placed in sub-zero temperatures (usually in the range of -20 to -80 degrees Celsius). When using ethanol, the ratio of ethanol to extract is often 10mL ethanol to 1g of oil. However this ratio often ranges between 5ml to 1g and 20ml to 1g.
During this process in the sub-zero temperatures, the lipids float to the top of the solution because of their lower solubility. The ideal time to leave the solution in cold temperatures is at least 24 hours.
There are multiple filters that the solution can go through such as paper filters and metal micro-filters. The lipids are filtered out of the solution through the filtration process and what is left is a high-purity distillate.
Why is winterization important in the cannabis and hemp oil extraction process?
To truly compete in the cannabis and hemp oil industry, winterization is a vital process. As mentioned previously, a winterized solution has more value than a solution that is not winterized.
Not only is value a factor, but customer satisfaction also plays a big role in this process. When an extract has fat and lipids left in it, it burns, vapes and tastes bad. Consumers will not buy this low-quality product again.
The saying “look good, feel good” does not only apply to people, it also applies to distillate. Everyone likes a shiny new product, not a cloudy and murky one. This is especially true for distillate consumers as transparency is an easy indicator of the level of purity in an extract. To ensure that a product can compete in the cannabis industry, winterization must be included in the extraction process.
Want to learn more about the winterization process and how Maratek can help automate and perfect the process with our expertly engineered Turnkey Automatic Winterization System (TAWS)? Contact us today. We would love to answer any questions that you may have.
Winterization of Oils to Remove Fats and Waxes
Cannabis and hemp are botanically complex, containing a rich assortment of carbohydrates, insoluble fibres, proteins, chemicals, and vitamins. Among the most valuable constituents of the Cannabis sativa and indica plant species are—of course—cannabinoids like cannabidiol (CBD) and tetrahydrocannabinol (THC). Extracting these compounds from the raw plant material and purifying it into a high-purity end-product requires a multi-step workflow, from harvesting through to winterization.
Why Winterize Oils?
Fractional distillation alone will often fail to remove unwanted lipids like fats and waxes from oil extracts. This can have a direct effect on the end-product, diluting potency, reducing clarity, and generally leading to a distillate of overall reduced quality.
Winterization is key step in the extraction and purification of oils derived from cannabis and hemp. It involves the fractional crystallization of the extract using butane or high proof ethanol at cryogenic temperatures, or liquid carbon dioxide (CO2). Cold ethanol winterization is usually preferred as it is relatively inexpensive and quick, but it tends to produce darker extracts. We compared the impact of different extraction methods in a recent article: What is the Winterization Process?
In cold ethanol winterization, the raw, unfiltered extract is mixed in the alcohol solution until fully combined then cooled to temperatures approaching -80°C. Critical winterization parameters include cooling rate, temperature of crystallization, and molecular mobility within the oil mass, as these variables directly influence the precipitation of solid fats and waxes.
Once winterization of oils and fats is complete, the heterogeneous crude mixture can then be filtered using traditional filteration equipment. It may also be decarboxylated to convert cannabidiolic acid (CBDA) into CBD, producing higher concentration extracts. The filtrate is concentrated down to separate the ethanol from the cannabinoid oil; a term often referred to as post-winterization
The type of equipment used in post-winterization depend on the method used. Both sub- and supercritical CO2 extraction typically use falling film evaporators, but such a bulky and large-scale apparatus is unsuitable for modern cannabis facilities.
Cannabis today represents a booming global industry contributing billions of dollars to economies around the world. Producers looking to drive the bottom line and increase profit margins without compromising the quality of their product offering must be able to distil and purify large volumes of oil quickly and effectively. The falling film evaporator is unfortunately unsuitable for such an initiative, particularly for small-scale laboratories looking to produce high-quality cannabinoid oils on a budget.
At Ecodyst, we have pioneered a new extraction and platform based on a proprietary cooling technology that maximises yields, quality, and time. If you would like to learn more about how our evaporators are used in post-winterization processes, why not contact a member of the team today?